From 1980 through the early '90's, the nut material was Plastic. Reference: Greg Gagliano's G&L webpages.
Also, see this post: Was Brass nut ever offered as original?.
In the late '80s, the steel Wilkerson Roller Bearing Nut was an option for all instruments. Reference: Album: January 1, 1988 Pricelist.
Also, this same Pricelist indicates that the SC-3 came with a Bone nut. However, I have never seen any SC-3s or any listings of them indicating that any of them had factory installed Bone nuts.
When G&L first offered the Graph-Tech graphite nut it was the stock nut on the Legacy Special in 1993. Reference: Album: 1993-94 Catalog.
At the time the stock nut for most of the other guitars was Micarta ("High-Tech" Plastic). Later,
the graphite nut became the stock nut for the Comanche and S-500 models and an option for the
other models.
In September 2009, G&L switched from the Micarta nut to a 100% Natural Bone nut on all models, including the Comanche,
the Legacy Special and the S-500. The Graph-Tech nut remains listed as an option for all instruments. Reference: Correction on nut material used by G&L.
NOTE: This information was researched by me using the reference sources indicated. If anyone has any additional information which can add to or correct this information please contact me with details.
Nut Material used over the years at G&L
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Nut Material used over the years at G&L
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Got a G&L question? Check out the: G&L Knowledgebase
Current G&L Specifications and Options